How to Send Money From PayPal to the IRS

1. Apply for a PayPal debit card. The PayPal debit card links your PayPal account balance to a MasterCard. Log in to your PayPal account; click 'Withdraw,' then click 'Use Debit Card.' Follow the instructions to apply for the card.
2. Activate the PayPal debit card. Once you receive your debit card in the mail, activate it by logging in to the PayPal website or by calling the number on the front of the card. To select a PIN, you have to activate the card online.
3. Go to OfficialPayments.com to make a payment to the IRS using your PayPal debit card. There is a 2.35 percent fee to use this service. Select the type of payment you wish to make, enter the required information and pay with your PayPal debit card. The amount will be withdrawn from your PayPal balance.